等温吸附量计算方法的推导及应用
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陈元千(1933—),男,河南兰考人,教授级高级工程师,1952年考入清华大学石油工程系,1956年毕业于北京石油学院钻采系, 长期从事油气藏工程、油气田开发和油气储量评价工作。联系电话:15910321810,E-mail:tcy-1994@163.com。

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Derivation and application of isothermal adsorption rate calculation method
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    摘要:

    等温吸附方程和等温累积吸附方程是描述页岩气和煤层气吸附规律的2个重要理论方程。前者描述的是不 同压力下的等温吸附量,后者描述的是不同压力下的等温累积吸附量。应当指出,构成等温吸附量曲线中不同压 力下的数据点,不是利用实验测定直接得到的,而是利用理论公式计算得到的。尽管在中外,尤其是中国,目前已 有若干计算等温吸附量的方法,但多因在理论推导过程中存在不正确性和不可靠性,而导致计算公式和计算结果 的错误,并引出了所谓过剩吸附量的不正确概念,这样也就谈不上为页岩吸附气和煤层吸附气的资源评价提供可 靠的饱和累积吸附量数据。为此,基于气体状态方程,利用气体的物质守恒原理,经严格的推导,得到计算等温吸 附量的3种方法。同时,提出了判断是否达到饱和吸附状态的判断因子。页岩和煤层吸附实验资料的应用结果表 明,新建的计算方法和判断因子是正确、有效的。

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    Isothermal adsorption equation and isothermal cumulative adsorption equation are two important theoretical equation that describe the adsorption rule of shale gas or coal bed methane. The former describes isothermal adsorption rate at different transient pressures,and the latter describes the cumulative isothermal adsorption rate curves at different pressures. It should be pointed out that the different data points on the isothermal adsorption curve are not directly obtained through experimental tests,but are obtained by theoretical calculation formulas. Although some methods for calculating the isotherm adsorption rate have been published at home and abroad,especially in China,incorrectness and uncertainty during the theoretical derivation process lead to errors in calculation formulas and calculation results,and the concept of excess adsorption was not correct,which make it impossible to provide reliable saturated cumulative adsorption data for the evaluation of adsorption gas resources of shale and coal bed. According to the gas state equation,using the principle of material conservation of gas,three methods for calculating isothermal adsorption rate were obtained after strict derivation. The judgment factor for determining whether the state of saturated adsorption rate is reached was proposed. The application of shale and coal bed adsorption experimental data shows that the new calculation method and judgment factor are correct and effective.

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陈元千,汤晨阳,陈奇.等温吸附量计算方法的推导及应用[J].油气地质与采收率,2018,25(6):56~62

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  • 在线发布日期: 2019-01-17