耐温抗盐缔合聚合物的合成及性能评价
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曹绪龙,男,教授级高级工程师,博士,从事油田提高采收率技术研究。联系电话:(0546)8715384,E-mail:caoxulong.slyt@sinopec.com。

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国家科技重大专项“高温高盐油田提高采收率技术”(2011ZX05011)。


Synthesis and properties of heat-tolerance and salt-resistance hydrophobically associating water-soluble polymer
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    针对胜利油区三类油藏高温高盐的环境,采用胶束聚合法合成了一种耐温抗盐缔合聚合物HAWSP,研究了引发剂、表面活性剂、缔合单体DiC8AM物质的量分数及耐温抗盐功能单体AMPS-Na质量分数对HAWSP合成的影响,将其分子结构进行核磁共振氢谱表征,并对其溶液性能进行评价。HAWSP的最佳合成条件为:复合引发剂为Y4,表面活性剂为NS,DiC8AM物质的量分数为1.4%~1.6%,AMPS-Na质量分数为15%~17.5%。核磁共振氢谱证实HAWSP由AM,DiC8AM和AMPS-Na共聚而成。随着溶液中钙镁离子质量浓度的增加,HAWSP溶液的粘度保留率为55%~60%,而抗盐高分子质量聚合物PAM溶液的仅为30%~40%;在90 ℃高温下经120 d老化后,质量浓度为1 500 mg/L的HAWSP溶液的粘度为15 mPa?s,而相同质量浓度的PAM溶液在老化时间超过60 d后产生沉淀,HAWSP的耐温抗盐、老化稳定和驱油性能明显优于PAM,原油采收率提高幅度也明显高于PAM,可用作三次采油驱油剂。

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    The heat-tolerance and salt-resistance hydrophobically associating water-soluble polymers is successfully synthesized by means of micellar copolymerization. The effects of initiator, solubilization surfactant, hydrophobic monomer and functional monomer content on tackify performance are studied. A preliminary evaluation is done on the heat-tolerance and salt-resistance performance,the long-term stability performance and oil displacement performance. With the increase of the concentration of calcium and magnesium ions in solution, the viscosity retention rates of HAWSP solutions are located in the range of 55%-60%, while the PAM’s rates only vary from 30% to 40%. After aging for 120 days at 90 ℃, the viscosity of HAWSP solution at the concentration of 1 500 mg/L is 15 mPa?s, while the PAM is precipitated after aging for more than 60 days. The experimental results show that the heat-tolerance and saltresistance copolymers have excellent viscous performance, long-term stability and good effect on oil displacement by using complex initiator Y4, surfactant NS, hydrophobic monomer molarity at 1.4-1.6 mol % and functional monomer AMPS-Na content of 15-17.5 wt%。

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曹绪龙,刘坤,韩玉贵,何冬月.耐温抗盐缔合聚合物的合成及性能评价[J].油气地质与采收率,2014,21(2):10~14

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  • 在线发布日期: 2015-06-10