堵剂颗粒溶液流变性的影响因素
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作者简介:王武超(1991—),男,陕西西安人,在读博士研究生,从事非常规油气藏开发及稠油热采研究。E-mail:wuchao172034@163.com。

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国家自然科学基金-中国石油化学工业基金“难采稠油多元热复合高效开发机理与关键技术基础研究” (U20B6003)。


Factors influencing rheological properties of plugging agent particle solutions
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    摘要:

    稠油热复合开采后期,储层中存留的热复合流体对堵剂颗粒溶液流变性的影响还不明确,从而限制了颗粒溶液在该阶段的应用。为此,依据流变性理论和黏浓公式,结合颗粒溶液黏浓变化规律,优选出一个能够准确描述SiO2 +聚合物分散体系的黏浓关系;利用流变仪、Zeta 电位分析仪和扫描电镜仪,开展了不同因素对SiO2 +聚合物分散体系流变性的影响及机理认识的研究。结果表明,SiO2 +聚合物分散体系的黏浓关系符合Krieger 和Dougherty 黏浓模型;随着温度或矿化度的增加,体系黏度减小;随着颗粒浓度或pH值的增大,体系黏度增大;添加阴离子和非离子表面活性剂的SiO2+聚合物分散体系黏度相差不明显,而添加阳离子表面活性剂的SiO2 +聚合物分散体系黏度明显大于其余2 种溶液的黏度;随着pH值减小,添加不同类型表面活性剂的颗粒溶液黏度均减小。因此,选择合适的颗粒溶液,为SiO2 +聚合物分散体系在稠油热采开发后期提高采收率的应用提供了理论基础。

    Abstract:

    The effect of the thermal composite fluid remaining in the reservoirs on the rheological properties of the plugging agent particle solution is still unclear at the late thermal composite development stage of the heavy oil reservoirs. Therefore, it limits the application of particle solutions in this stage. For this, based on the rheological theoretical model and viscosity-concentration formula,a viscosity-concentration relationship that can accurately describe the SiO2 + polymer dispersion system was preferably selected by combining the viscosity-concentration change of particle solutions. The effects of different factors on the rheological properties of the SiO2 + polymer dispersion system and the mechanism were investigated by using a rheometer,a Zeta potential analyzer,and a scanning electron microscope. The results show that the viscosity-concentration relationship of the SiO2 + polymer dispersion system is in accordance with the Krieger and Dougherty viscosity-concentration models. The viscosity of the SiO2 + polymer dispersion system decreases with increasing temperature or mineralization. The viscosity of the SiO2 + polymer dispersion system in-creases with increasing particle concentration or pH. The difference in viscosity between SiO2 + polymer dispersion systems with anionic and nonionic surfactants is not significant,while the viscosity of SiO2 + polymer dispersion system with cationic surfactants is significantly greater than that of the remaining two solutions. The viscosity of the particle solutions with different types of surfactants decreases as the pH decreases. Therefore,it is important to select a suitable particle solution to provide a theoretical basis for the application of SiO2 + polymer dispersion system in the late thermal composite development stage of thick oil reservoirs.

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王武超,刘慧卿,杨发荣,东晓虎,陈掌星,李禹.堵剂颗粒溶液流变性的影响因素[J].油气地质与采收率,2023,30(6):122~128

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  • 收稿日期:2023-04-02
  • 最后修改日期:2023-08-12
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  • 在线发布日期: 2023-12-21