页岩油微尺度流动油-固界面黏附作用机制
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刘晓宇(1993—),女,山东菏泽人,副研究员,博士,从事非常规油气地质研究。E-mail:liuxy2023.syky@sinopec.com。

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国家自然科学基金项目“陆相泥页岩层系成岩热演化过程中有机无机相互作用及其对储集空间形成演化的影响”(42272142)、“陆相富有机质页岩成烃动态演化与烃类赋存机理”(42090022),中国石化科技部项目“页岩油开发实验关键技术研究与应用”(P24159)。


Mechanism of oil-solid interface adhesion in micro-scale flow within shale oil reservoirs
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    摘要:

    针对中国苏北盆地溱潼凹陷阜宁组二段(阜二段)泥页岩储层,系统探讨了页岩油在微尺度流动油-固界面的黏附作用机制。通过详细分析泥页岩的矿物组成、孔隙结构及流体特征,结合原子力显微镜和激光共聚焦显微镜技术,揭示不同类型页岩中页岩油流动规律和油-固界面黏附作用机制。研究结果表明,页岩油在压力驱动下储层内呈现出明显的分组分动用特征,轻质组分优先动用吸附至页岩壁面,显著增强了油-固界面的黏附力,且随着压力增加,重质组分开始流动,并进一步提升了黏附力,但压力超过5 MPa后黏附力趋于稳定。油-固界面黏附力测试表明,在低压条件下纹层状泥岩和块状粉砂质泥岩是提高页岩油采收率的重点类型;而在高压条件下,纹层状泥岩对页岩油的吸附和解吸附作用机制成为未来提高溱潼凹陷阜二段页岩油采收率的关键研究方向。

    Abstract:

    This study focused on the mud shale reservoirs in the second Member of Funing Formation in Qintong Sag,Subei Basin of China,and systematically investigated the oil-solid interface adhesion mechanism of shale oil in micro-scale flow. Through de‐tailed analysis of the mineral compositions,pore structures,and fluid characteristics of shale,the flow patterns of shale oil and the oil-solid interface adhesion mechanism in different types of shale were revealed by atomic force microscopy(AFM)and laser confo‐cal microscopy. The findings indicate that shale oil in the reservoir exhibits distinct characteristics of selective production driven by pressure,whereby light components are preferentially adsorbed onto the shale walls,significantly enhancing the adhesion at the oilsolid interface. As pressure increases,heavy components start to flow,further augmenting the adhesion,but they stabilize once pressures exceed 5 MPa. Adhesion tests at the oil-solid interface demonstrate that laminated mudstone and massive silty mudstone emerge as key target shale types for enhancing shale oil recovery under low-pressure conditions. Under high-pressure conditions,the mechanism of adsorption and desorption of shale oil by laminated mudstone becomes the key research area for improving shale oil recovery in the second Member of Funing Formation in Qintong Sag.

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刘晓宇,黄振凯,昝 灵,姜志高,牛 骏,伦增珉.页岩油微尺度流动油-固界面黏附作用机制[J].油气地质与采收率,2025,32(3):51~59

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  • 收稿日期:2025-01-20
  • 最后修改日期:2025-03-14
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  • 在线发布日期: 2025-04-17
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