基于X射线衍射和毛细管吸吮时间的页岩储层黏土稳定剂评价方法
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何延龙(1987—),男,甘肃兰州人,副教授,博士,从事提高油气采收率与储层保护技术的教学与科研工作。E-mail:stpnet@126.com。

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Evaluation methods of clay stabilizer in shale reservoirs based on X-ray diffraction and capillary suction time
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    摘要:

    压裂液及其添加剂的差异化评价是页岩储层工程地质一体化开发过程的重要环节,黏土稳定剂又是添加剂中至关重要的一项,因此,黏土稳定剂的快速筛选对于页岩储层的保护和保证压裂效果具有重要作用。通过引入毛细管吸吮时间检测方法,结合X射线衍射得到的岩心样品矿物组成,加权得到页岩储层岩心样品的毛细管吸吮时间计算值。分别建立岩心样品的毛细管吸吮时间检测值、计算值与传统黏土稳定剂评价方法得到的阳离子交换容量的计算值、检测值的相关关系,发现其均与阳离子交换容量的检测值存在相同的变化趋势。通过引入比例系数,对毛细管吸吮时间检测值、计算值与阳离子交换容量的计算值进行拟合计算,得到对应的阳离子交换容量拟合检测值,分别将其与阳离子交换容量的实际检测值进行相对误差分析,发现其平均相对误差均小于5%。实验结果表明,岩心样品毛细管吸吮时间检测值与基于X射线衍射和标准矿物毛细管吸吮时间检测值得到的毛细管吸吮时间计算值均可评价和筛选黏土稳定剂,相较于传统阳离子交换容量评价方法,毛细管吸吮时间检测方法具有快速性、准确性,能更好地适用于页岩储层复杂的黏土矿物组成和极强的非均质性。

    Abstract:

    The differential evaluation of fracturing fluid and its additives is an important link in the integrated development process of shale reservoir engineering geology,and clay stabilizer is a crucial additive. Therefore,the rapid screening of clay stabilizers plays an important role in protecting shale reservoirs and ensuring fracturing effects. By introducing the detection method of capillary suction time(CST)and combining it with the mineral composition of core samples obtained by X-ray diffraction,the calculated CST of core samples from shale reservoirs was obtained by weighting. The correlation between the detected and calculated CST of core samples and the calculated and detected cation exchange capacity(CEC)obtained by the traditional clay stabilizer evaluation method was established,respectively. It was found that they all had the same changing trend as the detected CEC. By introducing the proportional coefficient,the detected and calculated CST was fitted with the calculated CEC,and the corresponding fitted detection value of CEC was obtained. The relative errors between them and detected CEC were analyzed,respectively,and it was found that the average relative errors were all less than 5%. The experimental results show that both the detected CST of core samples and the calculated CST based on X-ray diffraction and standard mineral CST detection value can be used to evaluate and screen clay stabilizers. Compared with the traditional CEC evaluation method,the CST detection method is rapid and accurate and is suitable for the complex clay mineral composition and strong heterogeneity of shale reservoirs.

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何延龙,王 鑫,薛小佳,黄 海,吴 江,刘晓庆,唐思源,虎志强.基于X射线衍射和毛细管吸吮时间的页岩储层黏土稳定剂评价方法[J].油气地质与采收率,2025,32(3):28~37

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  • 收稿日期:2023-11-28
  • 最后修改日期:2024-10-22
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  • 在线发布日期: 2025-06-19
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