Study on homogeneous and heterogeneous microemulsion acid plugging removal systems and mechanisms in low-permeability sandstone reservoirs
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摘要:
在油田开发过程中,低渗透砂岩油藏孔喉较小,易产生储层伤害问题。而微乳酸(MEA)体系中的乳液粒径为纳米级且具有极好的变形性,对低渗透储层具有更好的注入性与适应性,但微乳酸的相态与解堵效果之间的关系仍缺乏研究。为此,针对渤海某低渗透砂岩油藏,采用伪三元相图法制备由相同化学剂组成但相态不同的同质异型微乳酸,并通过室内实验和现场应用评价其解堵和腐蚀效果。此外,通过化学性能评价、微观形貌和吸附实验,分析微乳酸相态对解堵及腐蚀效果的影响机理。结果表明,通过调节水相和油相的体积比,微乳酸可以顺利地从双连续型转化为水包油(O/W)型和油包水(W/O)型,从而构建同质异型微乳酸体系。微乳酸体系对混合堵塞物具有良好的溶解效果,其中O/W型MEA体系解堵效果较传统酸液的高10%,且在矿场试验中可以将日产油量提高 53.44%。而 W/O 型 MEA 体系则表现出更低的腐蚀性,腐蚀速率仅为纯酸的47.78%。机理研究结果表明,O/W型MEA体系的强解堵性源于其强携油能力,可以更高效地剥离并携带堵塞物周围的原油,从而使酸液有效接触固体堵塞物。而 W/O型 MEA体系中油相对酸液的包裹性与乳化剂和轻质油在钢片表面的混合吸附产生的协同作用使其具有低腐蚀性。
Abstract:
Low-permeability sandstone reservoirs are more susceptible to form blockage during the oil development process due to their smaller pore throat. Microemulsion acids(MEAs)with nano-level droplets and great deformability have better injection ability and adaptability for low-permeability reservoirs. However,research is still lacking on the relationship between the phase state of MEAs and the plugging removal effect. Therefore,in view of the conditions of a certain low-permeability sandstone reservoir in the Bohai Sea,the pseudo-ternary phase diagram method was adopted to prepare homogeneous and heterogeneous MEAs composed of the same chemical agent but with different phase states,and its plugging removal and corrosion effects were evaluated through laboratory experiments and field applications. In addition,the influence mechanism of the MEA phase on the effect was analyzed through chemical property evaluation,microscopic morphology,and adsorption experiments. The results show that by adjusting the volume of water and oil phases,MEA can be smoothly transformed from the double continuous type to the oil-in-water(O/W)type and the oil-in-water(W/O)type,thereby constructing a homogeneous and heterogeneous MEA system. The MEA system has a good dissolution effect on the mixed blockage. Among them,the plugging removal effect of the O/W type MEA system is 10% higher than that of the traditional acid solution,and it can increase the daily oil production by 53.44% in the field experiment.However,the W/O type MEA system shows lower corrosiveness,with a corrosion rate of only 47.78% of that of pure acid. The results of the mechanism study show that the strong plugging removal property of the O/W MEA system stems from its strong oil-carrying capacity,which can more efficiently strip and carry the crude oil around the blockage,thereby enabling the acid solution to contact the solid blockage effectively. In the W/O type MEA system,the encapsulation property of oil relative to acid solution and the synergistic effect produced by the mixed adsorption of emulsifier and light oil on the surface of the steel sheet make it have low corrosiveness.