驱油剂乳化能力定量表征新方法
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邹积瑞(1988—),男,吉林农安人,讲师,博士,从事复杂油气藏提高采收率和微尺度流体科学研究。E-mail:zou_jirui@cup.edu.cn。

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New method for quantitatively characterizing emulsifying ability of oil displacement agents
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    摘要:

    驱油剂的乳化能力在化学驱油过程中起到至关重要的作用,但驱油剂乳化能力的定量表征难题至今仍未解决。针对这一难题,提出了一种旋转液诱导驱油剂-原油体系乳化的乳化能力定量表征新方法。通过测定不同转速下的乳化油率,绘制其动态曲线以确定表征驱油剂乳化能力的实验参数——乳化系数(EI)。乳化系数充分表征了驱油剂与原油乳化的起始乳化转速、起始乳化油率和乳化速度,能准确分辨和比较由驱油剂质量分数、驱油剂类型和原油性质变化引起的乳化能力差异。通过对比乳化系数发现:AEO9的乳化系数最大(1.184),SDS的乳化系数最小(0.320),驱油剂对CQ原油的乳化能力由强至弱的顺序为AEO9>SDBS>SCS>Na2CO3>AEO5>SDS;随着驱油剂质量分数的增加,乳化系数增大,驱油剂的乳化能力增强;驱油剂的乳化能力受原油性质的影响,由于SL原油中活性组分多,驱油剂对SL原油的乳化能力大于CQ原油。此外,多孔介质中表面活性剂-原油同注实验和表面活性剂驱油实验结果表明,高乳化系数的驱油剂在多孔介质中具有更强的原位乳化能力,乳化系数作为驱油剂乳化能力表征和评价的参数是合理的。

    Abstract:

    The emulsifying ability of oil displacement agents plays a crucial role in the chemical flooding process,but the quantita‐tive characterization of emulsifying ability remains unsolved. In response to this challenge,this paper presented a new method for quantitatively characterizing the emulsifying ability through emulsification of oil displacement agent-crude oil systems induced by rotating fluid. The method determined the experimental parameters(emulsification coefficient)characterizing the emulsifying ability of oil displacement agents by plotting the dynamic curve of emulsification oil rate at different rotational speeds. The emulsification coefficient fully characterized the initial rotational speed of emulsification,initial emulsification oil rate,and emulsification speed of oil displacement agents with crude oil and accurately distinguished and compared the differences in emulsifying ability caused by changes in the mass fraction of the oil displacement agent,type of oil displacement agent,and properties of the crude oil. By comparing the emulsification coefficients,it was found that AEO9 had the highest emulsification coefficient(1.184),while SDS had the lowest emulsification coefficient(0.320). The emulsifying ability of the oil displacement agents for CQ crude oil in descending order was as follows:AEO9>SDBS>SCS>Na2CO3>AEO5>SDS. As the mass fraction of the oil displacement agent increased,the emulsification coefficient increased,indicating an enhanced emulsifying ability. The emulsifying ability of the oil displacement agents was also influenced by the properties of the crude oil. Due to the higher content of active components in SL crude oil,the emulsifying ability of the oil displacement agents is greater for SL crude oil than for CQ crude oil. In addition,the results of co-injection experiments involving surfactants and crude oil in porous media,as well as surfactant flooding experiments,indicate that oil displacement agents with higher emulsification coefficients exhibit stronger in-situ emulsifying ability in porous media. Therefore,using the emulsification coefficient as a parameter to characterize and evaluate the emulsifying ability of oil displacement agents is reasonable.

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邹积瑞,岳湘安,李晓骁,邵明鲁,杨志国,安维青.驱油剂乳化能力定量表征新方法[J].油气地质与采收率,2025,32(3):154~166

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  • 收稿日期:2023-10-24
  • 最后修改日期:2024-11-14
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  • 在线发布日期: 2025-06-19
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