原油多重乳状液形成规律及影响因素
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刘建斌(1990—),男,陕西榆林人,讲师,博士,从事致密储层描述与渗吸增产、稠油油藏化学复合驱油机理、孔隙介质多相微观渗流 理论、分子动力学模拟等方面的研究。E-mail:deleap@163.com。

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Study on formation rules and influencing factors of multiple crude oil emulsions
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    摘要:

    油藏在成藏以及注水开发过程中会形成大量的W/O乳状液,这为后续化学驱提高采收率带来了诸多挑战。通过对原油乳状液(W/O、O/W和W/O/W)形成理论、W/O/W乳状液的性能变化规律以及失稳动态进行详细的研究,明确了原油多重乳状液的形成规律及影响因素。W/O乳状液的黏度随含水率的增大分为线性增大和指数式增大 2 个过程。油藏中化学剂乳化W/O乳状液形成的乳状液类型为W/O/W乳状液。W/O乳状液含水率越高,W/O/W乳状液的粒径越大,其性能主要受到粒径的大小以及 W/O 乳状液中水相动用程度的影响。化学剂动用 W/O 乳状液内部水相能力越强,形成的 W/O/W 乳状液粒径越小。化学剂浓度越高,乳化能力越强,动用内部水相能力越强。W/O/W乳状液的黏度则是受到其粒径、界面膜强度以及内部水相的影响。粒径越小、W/O液滴内部水相越少、界面膜强度越高,W/O/W乳状液的黏度越低。W/O/W乳状液的稳定性主要受到其粒径以及液滴聚并速度的影响。化学剂乳化形成的W/O/W乳状液粒径越小,液滴聚并越慢,其越稳定。化学剂浓度升高,初期脱水速度降低,但内部水相动用程度增大,所以最终脱水率和到达稳定脱水的时间均增加。油水比增大,W/O液滴的密度增大,初期脱水速度放缓。此外,W/O乳状液内部水相的利用程度也随着油水比的升高而降低,最终脱水率降低。温度升高,初期脱水速度加快,到达稳定脱水期的时间缩短,最终脱水率升高。

    Abstract:

    A large amount of W/O emulsions will be formed during reservoir formation and waterflood development,which brings many challenges to chemical flooding for the subsequent enhanced oil recovery. Therefore,the formation theory of crude oil emulsions(W/O,O/W,and W/O/W),the performance variation rules,and the instability behaviors of W/O/W emulsions were studied in detail to clarify the formation rules of multiple crude oil emulsions and their influencing factors. The viscosity increase of W/O emulsions can be divided into two processes with the increase in water content:linear increase and exponential increase. The W/O emulsion emulsified by chemical emulsification forms W/O/W emulsion in oil reservoirs. A higher water content of W/O emulsion indicates a larger droplet size of W/O/W emulsion. Its performance is mainly affected by the droplet size and the percentage of the produced water phase in the W/O emulsion. A stronger ability of the chemical agent to produce the internal water phase of the W/O emulsion means a smaller droplet size of the formed W/O/W emulsion. A higher mole concentration of chemical agents indicates a stronger emulsification ability and a stronger ability to produce the internal water phase. The viscosity of the W/O/ W emulsion is affected by its droplet size,the strength of the interfacial film,and the internal water phase. A lower droplet size means less water phase in the W/O droplet,higher interfacial film strength,and lower viscosity of W/O/W emulsion. The stability of W/O/W emulsion is mainly affected by its droplet size and droplet coalescence rate. The smaller droplet size of the W/O/W emulsion formed by the emulsification of chemical agents means a slower droplet coalescence rate and stronger stability. The initial dehydration rate decreases with the increase in chemical agent concentration. However,as the percentage of the produced water phase intensifies,the final dehydration rate and the time to reach the stable dehydration increase. With the increase in the oil-water ratio,the density of W/O droplets increases,and the initial dehydration rate slows down. In addition,the percentage of the produced water phase in the W/O emulsion decreases with the increase in the oil-water ratio,and the final dehydration rate decreases. As the temperature increases,the initial dehydration speed is accelerated,and the time to reach the stable dehydration stage is shortened. Finally,the final dehydration rate is increased.

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刘建斌,孙锦鹏,刘 顺,陈 鑫,卢温昌,邱 莹,杨嘉辉.原油多重乳状液形成规律及影响因素[J].油气地质与采收率,2025,32(5):178~189

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  • 收稿日期:2024-05-11
  • 最后修改日期:2025-07-20
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  • 在线发布日期: 2025-09-26
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