Nano-pore structure and fractal characteristics of tectonically deformed shale: A case study of Longmaxi Formation in Dabashan foreland thrust belt, northeastern Chongqing
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摘要:
作为中国南方页岩气勘探的重要层系,渝东北地区龙马溪组页岩经历了多期构造运动叠加改造,其纳米孔隙结构及分形特征尚未得到系统阐释。通过场发射扫描电镜纳米孔隙形貌观测以及基于Image J软件的孔隙结构定量表征,结合低温N2吸附实验获取的比表面积、孔体积及孔径分布等参数,采用FHH分形模型计算孔隙分形维数,系统揭示了渝东北地区大巴山前陆冲断带龙马溪组构造变形页岩纳米孔隙的分形特征及其影响因素。结果表明:研究区龙马溪组构造变形页岩主要发育有机质孔、粒间孔和粒内孔,储集空间以介孔为主,平均占比达59.30%。FHH分形模型计算结果显示,当相对压力P/P0=0.45时,龙马溪组构造变形页岩低温 N2吸附-脱附曲线开始出现回滞环,据此将分形维数 D 划分为低压区(P/P0<0.45)D1和高压区(P/P0≥0.45)D2,其中D1平均为2.609 0,D2平均为2.657 1,表明构造变形页岩纳米孔隙具有明显的分形特征。随着比表面积和孔体积的增大,分形维数增加,孔隙结构越复杂,非均质性越强;总有机碳含量与分形维数呈显著的正相关性,证实有机质热演化过程中生烃增压作用促进了纳米孔隙发育;石英含量与分形维数呈正相关性,反映刚性矿物对孔隙结构的保护效应;而黏土矿物与分形维数呈负相关性,表明塑性矿物在构造应力下通过颗粒重组降低孔隙结构的复杂性。
Abstract:
As an essential layer system for shale gas exploration in southern China,the shale of the Longmaxi Formation in northeastern Chongqing has undergone multi-stage tectonic movement superposition and transformation,and its nano-pore structure and fractal characteristics have not been systematically explained. Through the observation of nano-pore morphology by field emission scanning electron microscopy (FESEM) and the quantitative characterization of pore structures based on Image J software,combined with the specific surface area,pore volume,and pore size distribution parameters obtained by low-temperature N2 adsorption experiments,the FHH fractal model was used to calculate the pore fractal dimension. The fractal characteristics and influencing factors of nano-pores in the tectonically deformed shale of the Longmaxi Formation in the Dabashan foreland thrust belt in northeastern Chongqing were systematically revealed. The results show that the tectonically deformed shale of the Longmaxi Formation in the study area primarily develops organic matter pores,intergranular pores,and intragranular pores,with the reservoir space dominated by mesopores,accounting for an average of 59.30%. The calculation results of the FHH fractal model indicate that the low-temperature N2 adsorption-desorption curve of the tectonically deformed shale of the Longmaxi Formation begins to show a hysteresis loop when the relative pressure P/P0 = 0.45. Based on this,the fractal dimension D is divided into D1 in the low pressure region(P/P0 < 0.45)and D2 in the high pressure region(P/P0 ≥ 0.45). The average D1 is 2.609 0,and the average D2 is 2.657 1,indicating that the nano-pores of the tectonically deformed shale have obvious fractal characteristics. With the increase in specific surface area and pore volume,the fractal dimension also increases;the pore structure becomes more complex,and heterogeneity is stronger. There is a significant positive correlation between the total organic carbon content and the fractal dimension,which confirms that the hydrocarbon generation and pressurization during the thermal evolution of organic matter promote the development of nano-pores. The quartz content is positively correlated with the fractal dimension,reflecting the protective effect of rigid minerals on pore structure. Clay minerals are negatively correlated with fractal dimension,indicating that plastic minerals reduce the complexity of pore structure through particle recombination under tectonic stress.