超临界CO2-纳米聚硅提高水驱油藏采收率的作用机制
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张相春(1982—),男,安徽萧县人,副教授,博士,从事非常规油气提高采收率的科研与教学工作。E-mail:l_spring_2004@126.com。

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Mechanism of supercritical CO2-nano-polysilicon composite systems to enhance oil recovery of oil reservoir by water flooding
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    摘要:

    针对长庆油田某区块致密低渗透水驱油藏采收率低的难题,研制超临界CO2-纳米聚硅复合驱替液,探究其驱油机制及提升采收率的效果。采用聚2 -丙烯酰胺基-2-甲基丙磺酸(PAMPS)对SiO2进行原位表面修饰,制备出具有强吸附能力和界面活性的纳米聚硅颗粒。通过岩心驱替实验,对比研究混相和非混相条件下,不同质量分数(1%、2%、3%、4%和5%)纳米聚硅与超临界 CO2复合体系的驱油性能。通过实验监测采收率变化,分析纳米聚硅对岩石润湿性、界面张力及渗流特性的影响。混相条件下,超临界CO2主导驱油过程,水驱采收率仅为32.7%,复合体系可将采收率提升至70.0%以上。其中,质量分数分别为1%、2%和3%的低剂量纳米聚硅通过增强驱替液的黏弹性和界面活性,能够显著扩大油相波及面积,改善微观驱油效率;而质量分数分别为 4%和5%的高剂量纳米聚硅因颗粒堆积易堵塞渗流通道,导致驱替压力骤升,采收率增幅趋缓。非混相条件下,纳米聚硅的作用更为关键。通过降低超临界CO2与原油的界面张力、增加流体黏度,协同延长闭井时间,促进更多纳米聚硅吸附于含油岩石表面,将油湿表面转变为水湿或中性润湿状态,剥离残余油相,采收率从水驱的 31.6%升至 50%~60%。纳米聚硅的表面修饰使其具备双亲性,可在岩石-油-水界面形成稳定吸附层,削弱原油与岩石的附着力;超临界CO2则通过与原油混合,形成混相驱替,两者协同作用显著提升洗油效率。超临界CO2与纳米聚硅在驱替中优势互补,混相条件下CO2主导宏观驱油,非混相条件下纳米聚硅强化微观洗油,可共同实现采收率提升。

    Abstract:

    CO2主导宏观驱油,非混相条件下纳米聚硅强化微观洗油,可共同实现采收率提升。 In view of the low recovery of tight low-permeability oil reservoirs by water flooding in a certain block of Changqing Oilfield,a supercritical CO2-nano-polysilicon composite displacement fluid was developed to explore its oil displacement mechanism and the effect of enhanced oil recovery. Poly(2-acrylamido-2-methylpropane sulfonic acid)(PAMPS)was used for insitu surface modification of SiO2 to prepare nano-polysilicon particles with strong adsorption capacity and interfacial activity.Through core displacement experiments,the oil displacement performance of composite systems of nano-polysilicon with different mass fractions(1%-5%)and supercritical CO2 was compared under miscible and immiscible conditions. The recovery change was monitored in the experiments,and the effects of nano-polysilicon on rock wettability,interfacial tension,and flow characteristics were analyzed. Under miscible conditions,supercritical CO2 dominated the oil displacement process. The recovery of water flooding was only 32.7%,while the composite system increased it to over 70.0%. Among them,low-dose nano-polysilicon (1%-3%)significantly expanded the swept area of the oil phase and improved micro-scale oil displacement efficiency by enhancing the viscoelasticity and interfacial activity of the displacement fluid. However,high-dose nano-polysilicon(4%-5%)was prone to blocking flow channels due to particle accumulation,leading to a sharp increase in displacement pressure and a slowdown in recovery growth. Under immiscible conditions,nano-polysilicon played a more critical role. It reduced the interfacial tension between supercritical CO2 and crude oil,increased fluid viscosity,and synergistically prolonged the shut-in time,promoting more nano-polysilicon to adsorb on the oil-bearing rock surface,transforming the oil-wet surface into a water-wet or neutral-wet state,and stripping residual oil phases. Under these conditions,the recovery increased from 31.6% of water flooding to 50%-60%. The surface modification of nano-polysilicon gave it amphiphilicity,enabling it to form a stable adsorption layer at the rock,oil,and water interface and weaken the adhesion between crude oil and rock. Supercritical CO2 formed miscible displacement by mixing with crude oil. The synergistic effect of the two significantly improved oil washing efficiency. Supercritical CO2 and nano-polysilicon complemented each other in displacement. CO2 dominated macro-scale oil displacement under miscible conditions,while nano-polysilicon strengthens micro-scale oil washing under immiscible conditions,jointly achieving recovery improvement.

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张相春,文家鹏,尹良瑞,刘 辉,罗梓轩,王靖华.超临界CO2-纳米聚硅提高水驱油藏采收率的作用机制[J].油气地质与采收率,2025,32(6):118~127

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  • 收稿日期:2024-10-12
  • 最后修改日期:2025-08-12
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  • 在线发布日期: 2025-12-18
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