限域条件下陆相页岩储层中湿气的多尺度相行为研究
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任文希(1990—),男,四川南充人,副教授,博士,从事非常规储层油气赋存物理化学实验和理论研究。E-mail:renwx@swpu.edu.cn。

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Research on multi-scale phase behavior of wet gas in continental shale reservoirs under confinement conditions
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    陆相页岩储层具有多尺度孔隙结构,且烃类组成复杂,导致陆相页岩气表现出复杂的相行为,加剧了陆相页岩气储量评估和开采动态分析的难度。针对四川盆地侏罗系自流井组陆相页岩气,利用PR状态方程,考虑限域效应的影响,基于多尺度相平衡准则,结合粒子群-内点法,建立了考虑限域效应的多尺度相平衡计算方法,实现了全局平衡模拟。进一步利用恒质膨胀模拟衰竭式开发过程,研究不同压力条件下烃类在多尺度孔隙中的相态特征和相行为。研究发现:初始条件下,受限域效应的影响,较轻的组分趋向于在小孔中赋存,而较重的组分趋向于在大孔中赋存,进而导致孔径≤10 nm的孔隙中,烃类混合物对应的P-T相图向左上方发生偏移,临界温度降低,此外偏移程度随着孔径的增大而减小;在衰竭式开发过程中,随着储层压力的降低,小孔中较轻的组分容易进入大孔中富集,而小孔中较重的组分会在小孔中滞留。

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    The continental shale reservoir has a complex hydrocarbon composition and multi-scale pore structures,which further leads to the complexity of the phase behavior of continental shale gas. This intensifies the difficulty of reserve evaluation and dynamic analysis of continental shale gas exploitation. This study focused on the continental shale gas of the Jurassic Ziliujing Formation in the Sichuan Basin and developed a multi-scale phase equilibrium calculation method based on multi-scale phase equilibrium criterion,particle swarm optimization,and interior point method by using the PR equation and taking into account the influence of the confinement effect,so as to achieve the global equilibrium simulation. The constant composition expansion was used to simulate the depletion development process and study the phase characteristics and phase behavior of hydrocarbons in the multi-scale pores under different pressure conditions. The study finds that due to the confinement effects,the lighter components tend to exist in small pores,while the heavier components tend to exist in large pores under the initial conditions. As a result,the P-T phase diagram corresponding to the hydrocarbon mixture in pores with pore diameter ≤ 10 nm shifts to the upper left;the critical temperature decreases,and the degree of deviation decreases with the increase in the pore diameter. In the depletion development process,with the reduction of reservoir pressure,the lighter components in the pores can easily enter the large pore for enrichment,while the heavier components in the small pore remain in the small pore.

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任文希,叶 凯,王光付,郭建春,徐世乾,曾小军,田 杰.限域条件下陆相页岩储层中湿气的多尺度相行为研究[J].油气地质与采收率,2025,32(6):146~153

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  • 收稿日期:2025-01-16
  • 最后修改日期:2025-09-23
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  • 在线发布日期: 2025-12-18
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