金属类催化剂催化机理研究现状与展望
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徐正晓(1995—),男,山东阳谷人,讲师,博士,从事稠油热采及注气提高采收率工作。E-mail:xzx@cczu.edu.cn。

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Research status and prospects of catalytic mechanism of metal-based catalysts
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    摘要:

    火驱技术(ISC)作为低能耗、低排放的稠油开采手段,其应用受限于燃烧效率低及反应活化能高等问题。通过系统文献调研,综述了常规金属类催化剂、纳米级金属氧化物催化剂、多金属类复合催化剂等不同类型金属类催化剂对原油燃烧与蒸汽驱裂解的催化方法;结合热重分析、燃烧管实验等多维度数据,深入解析了金属类催化剂对稠油氧化反应的催化机理。研究表明:金属盐催化剂可显著降低反应活化能,其中硝酸铁可使稠油燃烧效率提高20%,环烷酸钴将低温氧化起始温度降低18 ℃;纳米级金属氧化物催化剂展现更强的催化活性,氧化铁纳米颗粒可使沥青质氧化温度降幅达160 ℃,活化能降低32.4%,而氧化镍纳米颗粒不仅能削减高温氧化活化能,更使燃烧前沿迁移速度提升;多金属类复合催化剂进一步突破性能极限,TiO2-ZrO2双金属催化剂将轻馏分产率较单组分提升>12%,Mo-Ni-W三金属纳米颗粒催化剂仅用5 h即实现50%的采收率,同时显著降低硫含量。综上,金属类催化剂通过大幅降低活化能与氧化温度,有效提升燃料沉积量与燃烧效率。其中氧化铁纳米颗粒及多金属类复合催化剂优势突出,但工业化应用仍需攻克高温失活、纳米颗粒滞留及H2S生成等关键瓶颈。

    Abstract:

    In-situ combustion (ISC),as a low-energy-consumption and low-emission method for heavy oil recovery,faces limitations in application due to the low combustion efficiency and high reaction activation energy. The catalytic methods of different types of metal catalysts,including conventional metal catalysts,nanometal oxide catalysts,and multi-metal composite catalysts,for crude oil combustion and steamflooding cracking were summarized through a systematic literature review. Combined with multidimensional data such as thermogravimetric analysis and combustion tube experiments,the catalytic mechanisms of metal catalysts in heavy oil oxidation reactions were thoroughly analyzed. Key findings reveal that metal salt catalysts significantly reduce reaction activation energy,among which iron nitrate can increase the combustion efficiency of heavy oil by 20%,and cobalt naphthenate can reduce the starting temperature of low-temperature oxidation by 18 °C. Nanometal oxide catalyst exhibits superior activity:Iron oxide nanoparticles reduce the asphaltene oxidation temperature by up to 160 °C and decrease activation energy by 32.4%;nickel oxide nanoparticles not only reduce high-temperature oxidation (HTO) activation energy but also accelerate combustion front velocity. Multi-metal composite catalysts further enhance performance:The TiO2-ZrO2 bimetallic catalyst increases light fraction yield by >12% compared to single components,and the Mo-Ni-W trimetallic catalyst achieves 50% oil recovery within just 5 hours,while significantly reducing sulfur content. In summary,metal catalysts markedly improve fuel deposition and combustion efficiency by drastically reducing activation energy and oxidation temperatures. Iron oxide nanoparticles and multi-metal composite catalysts demonstrate exceptional potential,yet overcoming critical challenges,such as hightemperature deactivation,nanoparticle retention,and H2S generation,remains imperative for industrial-scale implementation.

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徐正晓,赵长虹,陶 磊,刘 洋,张 娜,白佳佳,史文洋,李国华,李东旭.金属类催化剂催化机理研究现状与展望[J].油气地质与采收率,2025,32(6):154~165

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  • 收稿日期:2024-10-01
  • 最后修改日期:2025-08-13
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  • 在线发布日期: 2025-12-18
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