泥页岩储层等温吸附测试异常探讨
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林腊梅,女,讲师,博士,从事非常规油气资源勘探与评价工作。联系电话:15954813610,E-mail:llmls@sina.com。

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国土资源部全国油气资源战略选区调查与评价专项“页岩气调查和勘探开发实验分析测试技术研究”(2009GYXQ15)。


Study on abnormal curves of isothermal adsorption of shale
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    摘要:

    页岩气与煤层气的等温吸附特征既有相似性,又存在较大差异。目前页岩气等温吸附测试仍沿用煤层气相关测试规范,没有针对页岩气的等温吸附实验仪器。泥页岩储层等温吸附实验中普遍存在等温吸附曲线异常的现象,因此对常见的泥页岩储层等温吸附曲线异常现象进行了归纳,分析了导致异常的原因,并提出相应的改进建议。研究结果表明,在高压段,地层条件下由于甲烷处于超临界状态,吸附态气体不发生液化凝聚,造成测试曲线明显偏离Langmuir等温吸附模型,且特征参数失真,因而基于凝聚机理的Langmuir等温吸附模型在高压段不再适用,但该异常可通过模型改进或实验数据校正来消除;在低压段,通常由于泥页岩储层的吸附气含量远小于煤层气,而测试仪器精度难以满足要求,或泥页岩储层粘土矿物含量较高,在预处理中与水发生反应而影响吸附特征,可尝试通过增加测试样品量、预处理后充分脱水等方法来减少异常现象的发生。

    Abstract:

    Isothermal adsorption tests on shale always yield abnormal maps. On the basis of summary of the abnormal types, the study to probe the abnormal reasons is carried out and corresponding strategies are proposed. When the pressure is high, the methane in reservoir conditions is in supercritical state,the Langmuir model which is based on the condensation mechanism is no longer suitable to describe the adsorption features. This problem can be solved by amending the model or revising test data. When the pressure is low, the disorder on the measurement is caused by the adsorbed gas content in shale that is far lower than coal-bed gas,while the clay mineral content is much higher than that in coal-bed. In order to eliminate the disorder, the sample weight should be more and the sample preprocessing procedures should be amended.

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林腊梅,张金川,韩双彪,朱亮亮.泥页岩储层等温吸附测试异常探讨[J].油气地质与采收率,2012,19(6):30~32

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  • 在线发布日期: 2015-09-22