氮气吸附法—压汞法分析页岩孔隙、分形特征及其影响因素
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曹涛涛(1987—),男,河南柘城人,工程师,博士,从事非常规油气地质方面的研究。联系电话:15861496187,E-mail:515165359 @163.com。

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国家“973”计划“深层页岩气储集物性及含气性研究”(2012CB214704),国家自然科学基金项目“我国南方古生界高过成熟页岩 吸附特征与页岩含气性评价”(41273058),国家科技重大专项“深层高成熟烃源岩的容烃与排烃评价”(2011ZX05008-002-20)。


Characteristics of shale pores,fractal dimension and their controlling factors determined by nitrogen adsorption and mercury injection methods
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    利用氮气吸附法和压汞法联合表征下扬子皖南地区二叠系页岩的孔隙分布、孔隙度及分形特征。结果表明,研究区二叠系页岩中发育的孔隙以微孔和大孔为主,其中微孔的体积占页岩总孔隙体积的33.63%~81.08%,平均为56.45%;联孔孔隙度明显高于压汞孔隙度,平均增加96.06%;页岩在微孔和过渡孔—大孔区间均具有明显的分形特征,且微孔的分形维数比过渡孔—大孔更加分散,说明页岩中微孔的非均质性和复杂程度要高于过渡孔—大孔;微孔的孔隙度和分形维数与总有机碳含量、比表面积和生烃潜量呈正相关关系,与石英含量呈负相关关系;过渡孔—大孔的孔隙度和分形维数与总有机碳含量、石英含量呈负相关性,与比表面积和粘土矿物含量之间没有明显的相关性。随着埋深的增加,微孔的孔隙度和分形维数变化较小,过渡孔—大孔的孔隙度和分形维数明显降低, 且分形维数对埋深的敏感性高于孔隙度。

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    Institute of Petroleum Geology,Petroleum Exploration & Production Research Institute,SINOPEC,Wuxi City,Jiangsu Province,214126,China;3.Guangzhou Institute of Geochemistry,Chinese Academy of Sciences,Guangzhou City,Guangdong Province,510640,China;) Nitrogen adsorption method and mercury injection experiment were applied to characterize the joint pore distribution,porosity and fractal characteristics of Permian shales in south Anhui Province,the Lower Yangtze region. The results illustrate that:the pores in the Permian shales are dominated by micropore and macropore,and the volume of micropore accounts for 33.63% to 81.08% of the total pore volume with an average of 56.45%;the joint porosity is significantly higher than the porosity obtained by mercury injection method with an average increase of 96.06%;both the micropore and transition pore to macropore could generate obvious fractal characters for the Permian shales,and the fractal dimensions of the micropores are more dispersed than those of the transition pores to macropores,which indicates that the degree of heterogeneity and complexity of the micropore are higher than that of the transition pore to macropore;the porosity and fractal dimension of the micropore have positive correlation with TOC,specific surface area and hydrocarbon generation potential but negative correlation with quartz content;while the porosity and fractal dimension of the transition pore to macropore have negative correlation with TOC and quartz content,and no correlations with clay mineral content and specific surface area. With the increase of buried depth,the porosity and fractal dimension have no obvious variations for the micropore,but a certain decrease for the transition pore to macropore. The fractal dimension is more sensitive than the porosity to the buried depth.

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曹涛涛,宋之光,刘光祥,尹琴,罗厚勇.氮气吸附法—压汞法分析页岩孔隙、分形特征及其影响因素[J].油气地质与采收率,2016,23(2):1~8

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  • 在线发布日期: 2016-03-31