超高分三元共聚物流变特性及驱油性能
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祝仰文(1973—),男,山东郓城人,高级工程师,博士,从事三次采油方面研究。联系电话:13954617716,E-mail:zyzyw@163.com。

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国家科技重大专项“高温高盐油田化学驱提高采收率技术”(2016ZX05011-003)


Study on rheology and oil displacement properties of ultra high molecular weight terpolymer
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    摘要:

    常规水解聚丙烯酰胺在高温高盐油藏下粘度较低,将2-丙烯酰胺-2-甲基丙磺酸耐温抗盐单体引入聚丙烯酰 胺主链制备超高分三元共聚物是提高聚合物耐温抗盐特性的有效方法。对比研究常规水解聚丙烯酰胺和含2-丙 烯酰胺-2-甲基丙磺酸单体的超高分三元共聚物的基本物化性能、流变特性及驱油效果。在模拟水总矿化度为 32 868 mg/L的条件下,与常规水解聚丙烯酰胺相比,超高分三元共聚物流体力学有效直径增加30%以上,分子链更 加舒展,网络结构更加完整,粘度提高1倍以上。流变特性研究表明,超高分三元共聚物剪切流变方程中增稠系数 提高2倍,假塑性指数降低22%,因此,超高分三元共聚物具有更高的粘弹性,在地层运移时产生的拉伸粘度提高1 倍以上。双管物理模拟驱油实验结果表明,常规水解聚丙烯酰胺提高采收率仅为15.7%,超高分三元共聚物提高采 收率达24.1%,驱油效果更好,具有良好的应用前景。

    Abstract:

    The conventional hydrolyzed polyacrylamide(HPAM)flooding agent has very low viscosity in high temperature and high salinity reservoir. By introducing 2-acrylamido-2-methylpropane sulfonic acid(AMPS)monomer to the PAM backbone,the ultra-high molecular weight(UHMW)terpolymer was synthesized. This is an effective way to improve the temperature resistance and the salt tolerance performance of the polymer. The basic physicochemical properties,rheological properties and oil displacement effect of conventional HPAM and UHMW terpolymer with AMPS monomer were studied.Compared with the conventional HPAM,the effective diameter of UHMW terpolymer was increased by more than 30% at 32 868 mg/L salinity of the simulated water. The molecular chain was more stretched and the network structure were more complete,and the viscosity was more than doubled. Rheological studies show that the thickening coefficient of the UHMW terpolymer shear rheological equation increased by 2 times,and the power-law index decreased by 22%. Therefore,the UHMW terpolymer has higher viscoelasticity,and the tensile viscosity caused by its migration in the formation was more than doubled. The double-sand-filling-tube model experiment shows that the conventional HPAM can only enhance oil recovery by 15.7%,while the UHMW terpolymer can enhance oil recovery by 24.1%. The UHMW terpolymer has better oil displacement effect and has good prospect of application.

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祝仰文.超高分三元共聚物流变特性及驱油性能[J].油气地质与采收率,2018,25(6):78~83

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  • 在线发布日期: 2019-01-17