纳米颗粒对CO2泡沫体系稳定性的影响
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曲海莹(1994—),女,河南洛阳人,在读硕士研究生,从事油田化学与提高原油采收率方面的研究。联系电话:18813035398,Email: qhy398@163.com。

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国家自然科学基金项目“CCUS地质封存中CO2-咸水-地层岩-油井水泥相互作用机理的研究”(51604288),中国石油大学(北京)拔尖人才科研启动基金项目“二氧化碳地质封存中泄漏风险的研究”(2462015YJRC024)。


Effect of nanoparticle on stability of CO2 foam flooding system
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    摘要:

    纳米颗粒稳泡技术是一项新的提高采收率技术,目前仍处于室内研究阶段。对纳米颗粒稳泡技术的研究背景、作用机理、性能评价及驱油效果进行综述,结果表明,纳米颗粒与表面活性剂分子能产生协同作用,抑制CO2气泡的破灭、聚并和歧化,延长液膜的排液时间,延缓泡沫破裂速度,提高CO2泡沫体系在驱油过程中的稳定性。纳米颗粒/表面活性剂复配体系的半衰期是单一表面活性剂体系的2.5倍以上;经表面改性的纳米颗粒/表面活性剂复配体系可提高原油采收率7%~10%,最高可达30%以上。然而,过量的纳米颗粒会导致CO2泡沫体系的表面张力增加,发泡性能变差,泡沫体积和波及体积减小;不同种类的纳米颗粒与表面活性剂复配产生不同的协同作用。因此,纳米颗粒/表面活性剂复配体系的筛选与评价,是纳米颗粒稳泡技术的关键。

    Abstract:

    The nanoparticle-stabilized CO2 foam flooding is a new technique in enhanced oil recovery(EOR),and it is still at the laboratory research stage. In this study,the research background,mechanisms,performance evaluations,and oil displacement efficiency of the nanoparticle-stabilized CO2 foam flooding are reviewed. The results show that nanoparticles would synergize with certain surfactant molecules to inhibit CO2 bubble burst,coalescence and disproportionation,to prolong liquid film discharge time,and to delay internal foam rupture speed,which could improve the stability of CO2 foam system during the oil displacement. The half-life of combined system of nanoparticle and surfactant is over 2.5 times than that of single surfactant system. The oil recovery of the combined system after changing the surface properties could be increased by 7%-10%,with a maximum up to 30%. However,the excessive amounts of nanoparticles would also lead to the increase of surface tension of CO2 foam system,and resulting in the poor foaming property,the decrease of foaming volume and the swept volume. Different kinds of nanoparticles would have different synergistic effects on surfactants. Therefore,the screening and evaluation of the combined system of nanoparticle and surfactant is the key to the nanoparticle-stabilized CO2 foam flooding.

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曲海莹,刘琦,彭勃,罗聃,刘双星,刘柬葳.纳米颗粒对CO2泡沫体系稳定性的影响[J].油气地质与采收率,2019,26(5):120~126

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  • 在线发布日期: 2019-10-29